Development of a Miniaturized Ambient Glow Discharge Ionization Source and Its Application in Elemental and Molecular Analysis
نویسندگان
چکیده
منابع مشابه
Glow Discharge Mass Spectrometry : Trace Element Determinations in Solid Samples
Glow discharge mass spectrometry (GDMS) is a mature, versatile technique for the direct determination of trace elements in a variety of materials. The technique is an extension of the earliest forms of mass spectrometry. Processes inherent to the glow discharge, namely cathodic sputtering coupled with Penning ionization, yield an ion population from which semi-quantitative results can be direct...
متن کاملDetection of negative ions in glow discharge mass spectrometry for analysis of solid specimens.
A new method is presented for elemental and molecular analysis of halogen-containing samples by glow discharge time-of-flight mass spectrometry, consisting of detection of negative ions from a pulsed RF glow discharge in argon. Analyte signals are mainly extracted from the afterglow regime of the discharge, where the cross section for electron attachment increases. The formation of negative ion...
متن کاملAtmospheric pressure chemical ionization source. 1. Ionization of compounds in the gas phase.
A novel chemical ionization source for organic mass spectrometry is introduced. This new source uses a glow discharge in the flowing afterglow mode for the generation of excited species and ions. The direct-current gas discharge is operated in helium at atmospheric pressure; typical operating voltages and currents are around 500 V and 25 mA, respectively. The species generated by this atmospher...
متن کاملDouble Langmuir probe measurement of plasma parameters in a dc glow discharge
In this paper, plasma main characteristics such as electron mean temperature, electron number density, and oscillation frequency have been measured experimentally using the double Langmuir probe diagnostic system. In our experiment, the plasma was generated by applying the low pressure dc glow discharge in several common gases. The experimental results indicated the highest plasma density and o...
متن کاملA new pulsed glow discharge source with enhanced ion extraction for small non-conductive samples and atmospheric sampling
An ionization source designed to efficiently utilize sub-milligram quantities of electrically non-conducting compounds (i.e. oxides) for prolonged periods of mass spectrometric analysis is described. The source is coupled to a quadrupole ion trap mass spectrometer in this report, but could readily be modified for alternative types of mass spectrometers. The coaxial-design glow discharge ion sou...
متن کامل